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Toilet Duck Rimblock, Purple Wave
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: United KingdomToilet Duck Rimblock, Purple Wave cleans toilet bowls with every flush, prevents the build-up of limescale and fragrances for up to 4 weeks.
Purpose of product.
Usage: Toilet bowl cleanerStructure such as solid, liquid, aerosol etc.
Form: liquidDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 29, 2012Frimley Green
Camberley Surrey GU16 7AJ
United Kingdom
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.REACH COMPLIANCE
EU Hazard Classification Directive 67/548/EECHazard Symbols are used to classify dangerous substances.
Hazard SymbolsRisk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.
Risk PhrasesSafety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.
Safety PhrasesSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).-- 999999-92-1 -- 15-30 -- -- -- -- 157627-86-6 -- 5.0-10.0 -- -- -- -- 068585-34-2 -- 10.0-20.0 -- -- -- -- 068439-50-9 -- 0.5-1.0 -- -- -- -- 055406-53-6 -- -- -- -- -- 032210-23-4 -- 0.1-0.5 -- -- -- -- 013598-36-2 -- -- -- -- -- 009004-82-4 -- -- -- -- -- 009004-62-0 -- -- -- -- -- 007732-18-5 -- -- -- -- -- 007647-14-5 -- -- -- -- -- 007414-83-7 -- -- -- -- -- 002809-21-4 -- -- -- -- -- 002050-08-0 -- 0-0.5 -- -- -- -- 001843-05-6 -- 0.1-0.5 Xi -- -- -- -- 000138-86-3 -- Xi, N -- -- -- -- 000106-22-9 -- Xi, N -- -- -- -- 000091-64-5 -- 0.1-0.5 -- -- -- -- 000080-54-6 -- 0.1-0.5 Xn, N -- -- -- -- 000078-70-6 -- Xi -- -- -- -- 000068-04-2 -- -- -- -- -- 000052-51-7 -- Xi, Xn, N -- -- -- -- 000000-58-7 -- -- -- -- -- 000000-58-1 -- -- -- -- -- 000000-56-8 -- 5-15 -- -- -- -- 000000-00-2 -- -- -- -- -- 000000-00-1 -- -- -- -- Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.UN Global Harmonization Classification
Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Anionic surfactant(s) (unspecified) 999999-92-1 -- 15-30 -------- ------- ---- No Alcohols, C13-15-branched and linear, ethoxylated 157627-86-6 -- 5.0-10.0 -------- ------- ---- No (C10-C16) Alcohol ethoxylate, sulfated, sodium salt 068585-34-2 500-223-8 10.0-20.0 -------- ------- ---- No C12-14 Pareth-7 068439-50-9 500-213-3 0.5-1.0 -------- ------- ---- No 3-Iodo-2-propynylbutylcarbamate 055406-53-6 259-627-5 -- -------- ------- ---- No 4-Tert-Butylcyclohexyl Acetate 032210-23-4 250-954-9 0.1-0.5 H317 P261, P280, P302+P352, P333+P313, P362+P364, P501 No Phosphorus acid 013598-36-2 237-066-7 -- H290, H302, H314 ------- No Sodium laureth sulfate 009004-82-4 266-192-5 -- -------- ------- ---- No Hydroxyethyl cellulose 009004-62-0 - -- -------- ------- ---- Yes Water 007732-18-5 231-791-2 -- -------- ------- ---- No Sodium chloride 007647-14-5 231-598-3 -- -------- ------- ---- No Disodium Etidronate 007414-83-7 231-025-7 -- -------- ------- ---- No Etidronic acid 002809-21-4 220-552-8 -- H290, H318, H302 P234, P390, P406, P280, P305+P351+P338, P310, P264, P270, P301+P312, P330, P501 No Amyl Salicylate 002050-08-0 218-080-2 0-0.5 H302, H400, H410 P264, P270, P273, P301+P312, P330, P391, P501 No Benzophenone-12 001843-05-6 217-421-2 0.1-0.5 H317 ------- No Dipentene 000138-86-3 205-341-0 -- H226, H315, H317, H400, H410 ------- No Citronellol 000106-22-9 203-375-0 -- H315, H317, H319 ------- No Coumarin 000091-64-5 202-086-7 0.1-0.5 H301, H311, H317, H411 P260, P261, P264, P270, P272, P273, P280, P321, P363, P301+P312, P302+P352, P333+P313, P501 No Butylphenyl Methylpropional 000080-54-6 201-289-8 0.1-0.5 H302, H315, H317, H361, H412 P201, P202, P281, P308+P313, P405, P501 Yes Linalool 000078-70-6 201-134-4 -- H315, H317, H319 P280 No Sodium citrate (Trisodium citrate) 000068-04-2 200-675-3 -- -------- ------- ---- No 2-Bromo-2-nitropropane-1,3-diol 000052-51-7 200-143-0 -- H318, H315, H335, H312, H302, H411, H400 ------- No Butylphenyl Methylpropional-1 000000-58-7 -- -- -------- ------- ---- No Acrylic Copolymer Emulsion 000000-58-1 -- -- -------- ------- ---- No Nonionic surfactant(s) (unspecified) 000000-56-8 -- 5-15 -------- ------- ---- No Dye(s) (unspecified) 000000-00-2 -- -- -------- ------- ---- No Fragrance(s)/perfume(s) 000000-00-1 -- -- -------- ------- ---- No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Hazard Statements
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- Code
- Statement
- H226 : Flammable liquid and vapourH290 : May be corrosive to metalsH301 : Toxic if swallowedH302 : Harmful if swallowedH311 : Toxic in contact with skinH312 : Harmful in contact with skinH314 : Causes severe skin burns and eye damageH315 : Causes skin irritationH317 : May cause an allergic skin reactionH318 : Causes serious eye damageH319 : Causes serious eye irritationH335 : May cause respiratory irritationH361 : Suspected of damaging fertility or the unborn childH400 : Very toxic to aquatic lifeH410 : Very toxic to aquatic life with long lasting effectsH411 : Toxic to aquatic life with long lasting effectsH412 : Harmful to aquatic life with long lasting effects
- P201 : Obtain special instructions before useP202 : Do not handle until all safety precautions have been read and understoodP234 : Keep only in original containerP260 : Do not breathe dust/fume/gas/mist/vapours/sprayP261 : Avoid breathing dust/fume/gas/mist/vapours/sprayP264 : Wash … thoroughly after handlingP270 : Do not eat, drink or smoke when using this productP272 : Contaminated work clothing should not be allowed out of the workplaceP273 : Avoid release to the environmentP280 : Wear protective gloves/protective clothing/eye protection/face protectionP281 : Use personal protective equipment as requiredP310 : Immediately call a POISON CENTER or doctor/physicianP321 : Specific treatment (see … on this label)P330 : Rinse mouthP363 : Wash contaminated clothing before reuseP390 : Absorb spillage to prevent material-damageP391 : Collect spillageP301+P312 : IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwellP302+P352 : IF ON SKIN: Wash with soap and waterP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP308+P313 : If exposed or concerned: Get medical advice/attentionP333+P313 : If skin irritation or a rash occurs: Get medical advice/attentionP405 : Store locked upP406 : Store in a corrosive resistant/… container with a resistant inner linerP501 : Dispose of contents/container to
- GHS02 : FlammableGHS05 : CorrosiveGHS07 : IrritantGHS08 : Health HazardGHS09 : Environmentally Hazardous
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) SDS DATE : February 21, 2011 Measure of Alkalinity/Acidity of substance or preparation where a level of 7 is considered as neutral.
pH Levels5.1 -
SVHC declaration
Warning: This product contains Substances of Very High Concern (SVHC).
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Warnings
Risk of serious damage to eyes. Avoid contact with eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. If swallowed, seek medical advice immediately and show this container or label. Wash hands after handling product. For use only in toilet bowls. Contains Octabenzone, Butylphenyl Methypropional, Coumarin and Citronellol. May produce an allergic reaction.
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Safe use information
Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area.
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Acute health effects
Hazards Identification
Acute oral toxicity: May cause abdominal discomfort. Based on available data, the classification criteria are not met.Acute inhalation toxicity: No adverse effects expected when used as directed. Based on available data, the classification criteria are not met.Acute dermal toxicity: No adverse effects expected when used as directed. Based on available data, the classification criteria are not met.Skin corrosion/irritation: May cause skin irritation in susceptible persons. Based on available data, the classification criteria are not met.Eye damage/irritation: Risk of serious damage to eyes. -
Chronic health effects
No information provided.
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Carcinogenicity
Based on available data, the classification criteria are not met.
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Disposal information
Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Disposal should be in accordance with local, state or national legislation.
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First Aid
Inhalation: No special requirements.
Skin contact: Rinse with plenty of water. Get medical attention if irritation develops and persists.Eye contact: Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. Rinse immediately with plenty of water for at least 15 minutes. Get medical attention immediately.Ingestion: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
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